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They compost down okay Rooster, just don't put loads on in one go, layer them with other stuff.
I remember Snadger posted a great tip last year about avoiding clubroot in brassicas by diggin the hole for the seedling and lining it with rhubarb leaf before planting the seedling in it. Can't remember if it worked or not!
Yes, rhubarb leaves are poisonous to humans because they contain high concentration of oxalic acid. However, they can be composted successfully. Interestingly the oxalic acid doesn't seem to affect slugs and particularly snails - I find them often on the underside of the leaves.
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